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What are the steps to calculate cell potential (E°) using standard reduction potentials?

  1. Write the half-reactions. 2. Find the standard reduction potentials for each half-reaction. 3. Flip the sign of the oxidation half-reaction. 4. Calculate E°: E° = E°(reduction) + E°(oxidation).
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What are the steps to calculate cell potential (E°) using standard reduction potentials?

  1. Write the half-reactions. 2. Find the standard reduction potentials for each half-reaction. 3. Flip the sign of the oxidation half-reaction. 4. Calculate E°: E° = E°(reduction) + E°(oxidation).

What are the steps for electrolysis of NaCl?

  1. Identify the half-reactions (reduction and oxidation). 2. Determine the standard reduction potentials for each half-reaction. 3. Calculate the overall cell potential (E°cell). 4. Apply a voltage greater than or equal to the absolute value of E°cell to drive the non-spontaneous reaction.

Define redox reaction.

A reaction involving the transfer of electrons between chemical species.

Define oxidizing agent.

A substance that gains electrons and is reduced in a redox reaction.

Define reducing agent.

A substance that loses electrons and is oxidized in a redox reaction.

What is electromotive force (EMF)?

The force that pushes electrons in a redox reaction, measured in volts (V).

Define standard reduction potential.

The voltage associated with a reduction half-reaction under standard conditions.

Define galvanic (voltaic) cell.

An electrochemical cell that uses spontaneous redox reactions to generate electricity.

Define electrolytic cell.

An electrochemical cell that uses electrical energy to drive non-spontaneous redox reactions.

Define anode.

The electrode where oxidation occurs.

Define cathode.

The electrode where reduction occurs.

Label the anode, cathode, and direction of electron flow in a galvanic cell diagram.

Anode: Where oxidation occurs; Cathode: Where reduction occurs; Electron flow: From anode to cathode through the wire.

Label the anode, cathode, and direction of electron flow in an electrolytic cell diagram.

Anode: Where oxidation occurs; Cathode: Where reduction occurs; Electron flow: From the external power source to the cathode, and from the anode back to the power source.

Label the salt bridge in a galvanic cell diagram and explain its function.

Salt bridge: A tube containing an electrolyte (e.g., NaNO3NaNO_3) that connects the two half-cells; Function: Maintains charge neutrality by allowing ions to flow between the half-cells.